これ常識なんですかね?知りませんでした。。。

# \h copy
Command:     COPY
Description: copy data between a file and a table
Syntax:
COPY tablename [ ( column [, ...] ) ]
    FROM { 'filename' | STDIN }
    [ [ WITH ]
          [ BINARY ]
          [ OIDS ]
          [ DELIMITER [ AS ] 'delimiter' ]
          [ NULL [ AS ] 'null string' ]
          [ CSV [ HEADER ]
                [ QUOTE [ AS ] 'quote' ]
                [ ESCAPE [ AS ] 'escape' ]
                [ FORCE NOT NULL column [, ...] ]

COPY { tablename [ ( column [, ...] ) ] | ( query ) }
    TO { 'filename' | STDOUT }
    [ [ WITH ]
          [ BINARY ]
          [ OIDS ]
          [ DELIMITER [ AS ] 'delimiter' ]
          [ NULL [ AS ] 'null string' ]
          [ CSV [ HEADER ]
                [ QUOTE [ AS ] 'quote' ]
                [ ESCAPE [ AS ] 'escape' ]
                [ FORCE QUOTE column [, ...] ]

つまりこんなことができる、と。

copy (select * from 書籍 limit 10) to '/tmp/out.tsv'

なお、nullカラムは\Nで出力される模様。